# A Classic Formula For Pi Is Hidden in Hydrogen Atoms

Pi is the ratio between a circle’s circumference and its diameter, and is incredibly important in pure mathematics. But this was the first time scientists had found it “lurking” in the world of physics, when using quantum mechanics to compare the energy levels of a hydrogen atom.

Why was that exciting? Well, it revealed an incredibly special and previously unknown connection between quantum physics and maths.

“I find it fascinating that a purely mathematical formula from the 17th century characterises a physical system that was discovered 300 years later,” said one of the lead researchers at the time, Tamar Friedmann, a mathematician at the University of Rochester in the US.

The discovery was made when Carl Hagen, a particle physicist at the University of Rochester, was teaching a class on quantum mechanics and explaining to his students how to use a quantum mechanical technique known as the ‘variation principle’ to approximate the energy states of a hydrogen atom.

While comparing these values to conventional calculations, he noticed an unusual trend in the ratios.

He asked Friedmann to help him work out this trend, and they quickly realised that it was actually a manifestation of the Wallis formula for pi – the first time it had even been derived from physics.

“We weren’t looking for the Wallis formula for pi. It just fell into our laps,” said Hagen.

“It was a complete surprise,” added Friedmann. “I jumped up and down when we got the Wallis formula out of equations for the hydrogen atom.”

Since 1655 there have been plenty of proofs of Wallis’s formula, but prior to this, all had come from the world of mathematics.

You can see two pages from Wallis’s book *Arithmetica Infinitorum *below:

“This almost seems like magic,” wrote maths contributor Kevin Knudson for Forbes.

“That a formula for π is hidden inside the quantum mechanics of the hydrogen atom is surprising and delightful.”

“Nature had kept this secret for the last 80 years,” said Friedmann. “I’m glad we revealed it.”

We just can’t help but wonder what other secret connections are still out there, lurking between quantum mechanics and pure mathematics.

The results were published in the *Journal of Mathematical Physics.*

*A version of this article was first published in November 2015.*